isofthermodynamicanalysis,andresultsshowthatniandpcanco-depositonthecathodeintheformofni3p;therearesomeni3cphasesinthecoating,andccomesfromorganiccompoundwhichwasaddedinthebathandco2intheairthatwasdiolvedinwater.
experimentalresultsofproceparametersindicatethataseriesofre-ni-w-p-siccompositecoatingswithdifferentcontentswereobtainedbymeaofaropriateparameters,andcomponentscopesofthecoatingsaresic5~30wt,ni50~60wt,w10~25wt,p5~15wtandre5~10wt.thecontentsofw,pandsicinthecompositecoatingswereincreasedwhenchloride,oxideandsulfaterareearthwasaddedinthebathreectivelyortogether
.theadditionofsodiumhypophohatemustbearopriate,ifaddedmuch,wandsiccontentsinthecoatingsweredecreased,sotheadditionofsodiumhypophohatemustbecontrolled10~15g/l.currentdeity,temperatureandphvaluehavecoiderableeffectsonthecontentsofw,pandsicinthecompositecoatings.generally,currentdeity(dk)mustbecontrolled5~10a/dm2,ph6.0~6.5andtemperature55~65oc.besides,dkandphhaveagreateffectonthesurfacemorphologiesofthecoatings,andthecompositecoatingsgetcoarsewhendkandphwerehigh,onthecontrary,thecompositesgainfinecrystalwhendkandphwerelow.theagitatingintervaltimehaslittleeffectonni,wandpcontents,whileithascoiderableeffectonsiccontentinthedeposits.exteionofagitationandintervaltimewilldecreasesiccontentinthecomposites,sointervalandagitatingtimemustbecontrolled3miand4~5mireectively.
curvesofcathodicpolarizationdilaythatwhensicparticlesandrareearth(re)wereaddedinthebath,cathodicdepositingcurrentdeityofthecompositesincrea
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